Oxidation. Free radicals. Antioxidants. And the practical science tips that potato chips packaging design offers.
How do you like your potato chips? Crunchy and crispy, if you are like me! To keep them that way, we have to make sure the chips do not become rancid from oxidation.
Oxidation happens because fats and oils have very reactive atoms or groups of atoms with lone electrons called free radicals that react with oxygen. But where do these free radicals come from in the first place? They are…
“…initially formed by the loss of a hydrogen atom from a… fatty acid*… induced by ultraviolet light and heat.” (Source: Handbook of Food Science, Technology, and Engineering, Vol 2) *fatty acids are “building blocks of fats”
.
Once released, these reactive free radicals will set off a chain reaction, generating more free radicals and reacting with oxygen (if present).This is where the potato chips packaging comes in. They are opaque and blown up with nitrogen to reduce exposure to oxygen, and to block out ultraviolet light. The nitrogen also acts as an insulator against temperature changes that might induce free radical formation (read the details in the 1-Minute NomNom “Blowing up the bags of potato chips was no oxidant“).
The only way to stop the free radical reaction is to use antioxidants which work “sacrificially by donating a hydrogen atom to the reactive free radical and regenerating the original molecule“, thus terminating the chain reaction. Otherwise the chain reaction will be endless, and that is bad news for the storing of our food.
Understanding the science behind potato chips packaging design offers tips on we can prevent our foods with oils and fats such as peanut butter from going bad.
Firstly, we can “flush the headspace on peanut butter jars” with nitrogen gas. Secondly, we can keep them airtight to minimize exposure to oxygen. Thirdly, store them in dark containers and away from light. Lastly, do not wait too long to consume them; they are so yummi-licious anyway, what are you waiting for?
Like this? Set off a chain reaction for knowledge liking me to discover more. All you need is a minute a day to explore the world’s marvels through the phenomenon of food!
photos: in order – depositphotos/belchonock; rozelt; urbanbuzz; belchonock
ORIGINAL ====
1-Minute NomNom
How do you like your potato chips? Crunchy and crispy, if you are like me! To keep them that way, the puffy bags they are in have been designed to prevent the chips from becoming rancid from oxidation.
They are opaque and blown up with nitrogen to reduce exposure to oxygen, light and temperature that can trigger oxidation (read an overview in the 1-Minute NomNom “Blowing up the bags of potato chips was no oxidant“).
Reducing Oxygen Exposure
To understand the science behind why the design works, we start with an easy way to remember what oxidation is: the University of California suggests that we think of it as “adding… oxygen to a compound“.
Fats and oils have very reactive atoms or groups of atoms with lone electrons called free radicals. When exposed to oxygen, their…
“… unsaturated components are converted into hydroperoxides, which break down into volatile aldehydes, esters, alcohols, ketones, and hydrocarbons, some of which have disagreeable odours.” (Source: Encycolopaedia Britannica)
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This is where filling the bags of potato chips with nitrogen is useful. There is not only no exposure to oxygen, nitrogen is also an inert gas (i.e. chemically inactive) that does not react with the free radicals.
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Reducing Oxygen Exposure
But where do these free radicals come from in the first place? They are…
“…initially formed by the loss of a hydrogen atom from a… fatty acid*… induced by ultraviolet light and heat.” (Source: Handbook of Food Science, Technology, and Engineering, Vol 2) *fatty acids are “building blocks of fats”
Once released, these reactive free radicals will set off a chain reaction, generating more free radicals and reacting with oxygen (if present). This is where the opaque packaging helps to block out ultraviolet light. The nitrogen in the bags also acts as an insulator against temperature changes that might induce free radical formation.
Antioxidants
The only way to stop the free radical reaction is to use antioxidants which work “sacrificially by donating a hydrogen atom to the reactive free radical and regenerating the original molecule“, thus terminating the chain reaction. Otherwise the chain reaction will be endless, and that is bad news for the storing of our food.
Understanding the science behind potato chips packaging design offers tips on we can prevent our foods with oils and fats such as peanut butter and other types of crisps from going bad. Firstly, we can “flush the headspace on peanut butter jars” with nitrogen gas. Secondly, we can keep them airtight to minimize exposure to oxygen. Thirdly, store them in dark containers and away from light. Lastly, do not wait too long to consume them; they are so yummi-licious anyway, what are you waiting for?
Like this? Set off a chain reaction for knowledge liking me to discover more. All you need is a minute a day to explore the world’s marvels through the phenomenon of food!